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Summary: The experiment turned out well, and only a couple of instruments had an interference for formaldehyde. The NO CL monitor saw an interference and the LIF OHR saw diminished signal due to OH reacting with formaldehyde, but all other instruments ran smoothly. The LIF OHR was taken off of the experiment because the signal was too depleted to be useful. This helped save bag volume, so that the GTHOS could sample the entire experiment. Nitrooxyhydroperoxide, hydroxynitrate, and carbonylnitrate all formed in the dark and leveled off before turning on lights. When lights were turned on, nitrooxyhydroperoxide was oxidized via OH to nitrooxyhydroxyepoxide as expected.

Organization: 2014 FIXCIT Study Lab Affiliation: California Institute of Technology Chamber: Seinfeld chambers

Experiment Category: Gas phase chemical reaction Oxidant: Nitrate radical Reactants: ISOPRENE, Nitrogen dioxide, Ozone, Formaldehyde Reaction Type: Dark oxidation Relative Humidity: 5 Temperature: 26 Seed Name: N/A Pressure: 750</gco:CharacterString>
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                <gmd:URL>https://gdex.ucar.edu/datasets/d789037/dataaccess/</gmd:URL>
              </gmd:linkage>
              <gmd:protocol>
                <gco:CharacterString>https</gco:CharacterString>
              </gmd:protocol>
              <gmd:name>
                <gco:CharacterString>Data Access</gco:CharacterString>
              </gmd:name>
              <gmd:description>
                <gco:CharacterString>Related Link</gco:CharacterString>
              </gmd:description>
              <gmd:function>
                <gmd:CI_OnLineFunctionCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#CI_OnLineFunctionCode" codeListValue="download">download</gmd:CI_OnLineFunctionCode>
              </gmd:function>
            </gmd:CI_OnlineResource>
          </gmd:onLine>
        </gmd:MD_DigitalTransferOptions>
      </gmd:transferOptions>
    </gmd:MD_Distribution>
  </gmd:distributionInfo>
  <gmd:metadataConstraints>
    <gmd:MD_Constraints>
      <gmd:useLimitation>
        <gco:CharacterString>none</gco:CharacterString>
      </gmd:useLimitation>
    </gmd:MD_Constraints>
  </gmd:metadataConstraints>
  <gmd:metadataMaintenance>
    <gmd:MD_MaintenanceInformation>
      <gmd:maintenanceAndUpdateFrequency>
        <gmd:MD_MaintenanceFrequencyCode codeList="http://www.isotc211.org/2005/resources/Codelist/gmxCodelists.xml#MD_MaintenanceFrequencyCode" codeListValue="asNeeded">asNeeded</gmd:MD_MaintenanceFrequencyCode>
      </gmd:maintenanceAndUpdateFrequency>
    </gmd:MD_MaintenanceInformation>
  </gmd:metadataMaintenance>
</gmd:MD_Metadata>
