ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20130410_trans-beta IEPOX/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate
d789551
<p>Goals:<br/> IEPOX was introduced to hydrated ammonium sulfate at 50% RH, the chamber was cooled to to remove the IEPOX from the gas phase (no more traces in CIMS); this increased the RH to ~80%) then H2O2 was added and lights turned on to photolyze the IEPOX on the particles and walls.</p> <p>Summary:<br/> The organic aerosol as seen on AMS reacted nearly all away. Fragmentation products such as hydroxyacetone, glycolaldehyde, formic acid, acetic acid, and peroxyacetic acid were seen as products on CIMS</p> <p>Organization: Caltech Atmospheric Chamber<br/> Lab Affiliation: California Institute of Technology, Pasadena, CA<br/> Chamber: Near/Far Bag 2012-2015 (Tran)</p> <p>Experiment Category: Condensed-phase chemical reaction, Multiphase chemical reaction<br/> Oxidant: Hydroxyl radical<br/> Reactants: trans-beta IEPOX, hydrogen peroxide<br/> Reaction Type: Photooxidation, Heterogeneous oxidation, Other aqueous/aerosol phase<br/> Relative Humidity: 50-83<br/> Temperature: 16-22<br/> Seed Name: Ammonium sulfate<br/> Pressure: 750 Torr</p>
dataset
https://gdex.ucar.edu/datasets/d789551/
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https://gdex.ucar.edu/datasets/d789551/dataaccess/
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dataset
revision
2021-03-30
LABORATORY > LABORATORY
revision
2025-10-03
ICARUS > Integrated Chamber Atmospheric data Repository for Unified Science
revision
2025-10-03
EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES
revision
2025-10-03
2013-04-10
2013-04-10
publication
2023-08-23
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Creative Commons Attribution 4.0 International License
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NSF NCAR Geoscience Data Exchange
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2025-10-09T01:42:17Z