Identification

Title

Effect of isoprene emissions from major forests on ozone formation in the city of Shanghai, China

Abstract

Ambient surface level concentrations of isoprene (C(5)H(8)) were measured in the major forest regions located south of Shanghai, China. Because there is a large coverage of broad-leaved trees in this region, high concentrations of isoprene were measured, ranging from 1 to 6 ppbv. A regional dynamical/chemical model (WRF-Chem) is applied for studying the effect of such high concentrations of isoprene on the ozone production in the city of Shanghai. The evaluation of the model shows that the calculated isoprene concentrations agree with the measured concentrations when the measured isoprene concentrations are lower than 3 ppb, but underestimate the measurements when the measured values are higher than 3 ppb. Isoprene was underestimated only at sampling sites near large bamboo plantations, a high isoprene source, indicating the need to include geospatially resolved bamboo distributions in the biogenic emission model. The assessment of the impact of isoprene on ozone formation suggests that the concentrations of peroxy radicals (RO(2)) are significantly enhanced due to the oxidation of isoprene, with a maximum of 30 ppt. However, the enhancement of RO(2) is confined to the forested regions. Because the concentrations of NO(x) were low in the forest regions, the ozone production due to the oxidation of isoprene (C(5)H(8) + OH ->-> RO(2) + NO ->-> O(3)) is low (less than 2-3 ppb h(-1)). The calculation further suggests that the oxidation of isoprene leads to the enhancement of carbonyls (such as formaldehyde and acetaldehyde) in the regions downwind of the forests, due to continuous oxidation of isoprene in the forest air. As a result, the concentrations of HO(2) radical are enhanced, resulting from the photo-disassociation of formaldehyde and acetaldehyde. Because the enhancement of HO(2) radical occurs in regions downwind of the forests, the enhancement of ozone production (6-8 ppb h(-1)) is higher than in the forest region, causing by higher anthropogenic emissions of NO(x). This study suggests that the biogenic emissions in the major forests to the south of Shanghai have important impacts on the levels of ozone in the city, mainly due to the carbonyls produced by the continuous oxidation of isoprene in the forest air.

Resource type

document

Resource locator

Unique resource identifier

code

https://n2t.org/ark:/85065/d7251jxk

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

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keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

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End position

Dataset reference date

date type

publication

effective date

2011-10-20T00:00:00Z

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Use constraints

Copyright Author(s) 2011. This work is distributed under the Creative Commons Attribution 3.0 License

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None

Responsible organisations

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contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata date

2025-07-17T14:25:21.749352

Metadata language

eng; USA