Identification

Title

ICARUS Chamber Experiment: 2014 FIXCIT Study_20140127_trans-beta-IEPOX/methyl nitrite_Hydroxyl radical_No Seed_Trans-beta-IEPOX + OH, moderate NO, dry, no seeds

Alternative title(s)

d789023

Abstract

Goals:; Allow everyone to sample trans-beta-IEPOX for an intercomparison of sensitivities and a look at possible interferences; observe the products of IEPOX + OH oxidation, which we expect to include hydroxyacetone, glycolaldehyde, glyoxal, methylglyoxal, and C4H8O3 and C4H6O3 compounds. Summary:; Today's experiment went largely according to plan. We successfully injected a large amount of IEPOX (we estimate 60 to 70 ppbv) over the course of 2.5 hours. Following the injection, the CF3O- CIMS saw significant wall loss, totaling ~25% in 3 hours. This is similar to the wall loss observed during IEPOX experiments last summer (~7%/hour in the same bag with high levels of HNO3), which may imply that the walls are currently highly acidified. When lights were turned on, IEPOX reacted quickly; ~50% of the IEPOX remaining when lights were turned on reacted away within an hour, and a further 20% was lost in the next two hours. The CF3O- CIMS observed many of the expected oxidation products, including hydroxyacetone, glycolaldehyde, C4H8O3, C4H6O3, and C5H8O3. Glyoxal did see an increase in signal, though they also had high noise levels. O3 reached 150 ppbv by the end of the experiment, and AMS did not see significant nucleation or aerosol growth. Organization: 2014 FIXCIT Study; Lab Affiliation: California Institute of Technology; Chamber: Seinfeld chambers Experiment Category: Gas phase chemical reaction; Oxidant: Hydroxyl radical; Reactants: trans-beta-IEPOX, methyl nitrite; Reaction Type: Photooxidation; Relative Humidity: 5; Temperature: 25; Pressure: 750 Torr

Resource type

dataset

Resource locator

https://rda.ucar.edu/datasets/d789023/

protocol: https

applicationProfile: browser

name: Dataset Description

description: Related Link

function: information

https://rda.ucar.edu/datasets/d789023/dataaccess/

protocol: https

applicationProfile: browser

name: Data Access

description: Related Link

function: download

Unique resource identifier

code

codeSpace

Dataset language

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

environment

Keywords

Keyword set

keyword value

dataset

originating controlled vocabulary

title

reference date

date type

revision

effective date

2014-10-16

Keyword set

keyword value

LABORATORY > LABORATORY

originating controlled vocabulary

title

reference date

date type

revision

effective date

2025-06-10

Keyword set

keyword value

ICARUS > Integrated Chamber Atmospheric data Repository for Unified Science

originating controlled vocabulary

title

reference date

date type

revision

effective date

2025-06-16

Keyword set

keyword value

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES

originating controlled vocabulary

title

reference date

date type

revision

effective date

2025-05-23

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2014-01-27

End position

2014-01-27

Dataset reference date

date type

publication

effective date

2021-10-12

Frequency of update

notPlanned

Quality and validity

Lineage

Conformity

Data format

name of format

version of format

Constraints related to access and use

Constraint set

Use constraints

Creative Commons Attribution 4.0 International License

Limitations on public access

None

Responsible organisations

Responsible party

organisation name

UCAR/NCAR - Research Data Archive

full postal address

National Center for Atmospheric Research

CISL/DECS

P.O. Box 3000

Boulder

80307

U.S.A.

telephone number

(303)-497-1825

facsimile number

303-497-1291

email address

dattore@ucar.edu

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

NCAR Research Data Archive

full postal address

National Center for Atmospheric Research

CISL/DECS

P.O. Box 3000

Boulder

80307

U.S.A.

facsimile number

303-497-1291

email address

rdahelp@ucar.edu

web address

https://rda.ucar.edu/

name: NCAR Research Data Archive

description: The Research Data Archive (RDA), managed by the Data Engineering and Curation Section (DECS) of the Computational and Information Systems Laboratory (CISL) at NCAR, contains a large and diverse collection of meteorological and oceanographic observations, operational and reanalysis model outputs, and remote sensing datasets to support atmospheric and geosciences research, along with ancillary datasets, such as topography/bathymetry, vegetation, and land use.

function: downlaod

responsible party role

pointOfContact

Metadata date

2025-06-19T04:05:02Z

Metadata language