Identification

Title

Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set

Abstract

Isoprene affects new particle formation rates in environments and experiments also containing monoterpenes. For the most part, isoprene reduces particle formation rates, but the reason is debated. It is proposed that due to its fast reaction with OH, isoprene may compete with larger monoterpenes for oxidants. However, by forming a large amount of peroxy-radicals (RO2), isoprene may also interfere with the formation of the nucleating species compared to a purely monoterpene system. We explore the RO2 cross reactions between monoterpene and isoprene oxidation products using the radical Volatility Basis Set (radical-VBS), a simplified reaction mechanism, comparing with observations from the CLOUD experiment at CERN. We find that isoprene interferes with covalently bound C20 dimers formed in the pure monoterpene system and consequently reduces the yields of the lowest volatility (Ultra Low Volatility Organic Carbon, ULVOC) VBS products. This in turn reduces nucleation rates, while having less of an effect on subsequent growth rates.

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document

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Unique resource identifier

code

https://n2t.net/ark:/85065/d7vt1xfj

codeSpace

Dataset language

eng

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geoscientificInformation

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Text

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title

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reference date

date type

publication

effective date

2016-01-01T00:00:00Z

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publication

effective date

2024-07-01T00:00:00Z

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<style type="text/css"></style><span style="font-family:Arial;font-size:10pt;font-style:normal;" data-sheets-root="1">Copyright author(s). This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.</span>

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None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

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pointOfContact

Metadata on metadata

Metadata point of contact

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata date

2025-07-10T20:00:41.403825

Metadata language

eng; USA