edu.ucar.gdex::d789025 eng; USA utf-8 dataset NSF NCAR Geoscience Data Exchange datahelp@ucar.edu https://gdex.ucar.edu NSF NCAR Geoscience Data Exchange The Geoscience Data Exchange (GDEX), managed by the Computational and Information Systems Laboratory (CISL) at NSF NCAR, contains a large collection of meteorological, atmospheric composition, and oceanographic observations, and operational and reanalysis model outputs, integrated with NSF NCAR High Performance Compute services to support atmospheric and geosciences research. download pointOfContact 2025-06-19T15:12:40Z ISO 19115 Geographic Information - Metadata ISO19115:2003/Cor 1 2006 https://doi.org/10.5065/phta-9y15 https://doi.org/10.5065/phta-9y15 https Related Resource #1 ICARUS Dataset at UC-Davis ICARUS Chamber Experiment: 2014 FIXCIT Study_20140121_ISOPRENE/hydrogen peroxide_Hydroxyl radical_No Seed_Isoprene + OH, low NO, dry, no seeds, lower initial concentration d789025 2021-10-12 publication Wennberg, Paul O. author Seinfeld, John H. author Crounse, John D. author Nguyen, Tran B. author NSF National Center for Atmospheric Research publisher Goals: Study isoprene low NO chemistry. The experiment will be similar to the experiment run on 01/02/2014, but the loading will be lower, so as to limit RO2 + RO2 chemistry. Summary: We injected isoprene initially and like the experiment run on 01/19/2014 there was ISOPOOH contamination during the injection. We decided given the goals of the experiment to flush the bag for several hours to remove the ISOPOOH. After several hours of flushing the ISOPOOH was roughly around 200 ppt (see the worked up data for a more precise number). The source of contamination was found, and everything was cleaned again. No ISOPOOH was injected during the second injection of isoprene. Because we started the experiment later (i.e., after rush hour), the NO background was a lot lower than previous experiments (~10 ppt in the beginning). The lower isoprene loading in this experiment allowed for the HO2 pathway to dominate over the RO2 pathway and allowed for later generation products to form. During the experiment we saw ISOPOOH form and decay away. Unexpectedly IEPOX also formed and decayed away. There seemed to be a lower than expected amount of IEPOX formed. Perhaps wall loss was greater in this experiment than on 01/02/2014. For the PTR-MS and GC-FID, we trapped ISOPOOH/IEPOX at -40 C, so that yields of MVK and MACR for the experiment could be determined without the ISOPOOH/IEPOX interference. Organization: 2014 FIXCIT Study Lab Affiliation: California Institute of Technology Chamber: Seinfeld chambers Experiment Category: Gas phase chemical reaction Oxidant: Hydroxyl radical Reactants: ISOPRENE, hydrogen peroxide Reaction Type: Photooxidation Relative Humidity: 5 Temperature: 27 Pressure: 750 Torr completed datahelp@ucar.edu pointOfContact notPlanned dataset https://gdex.ucar.edu/images/ds_logos/default_200_200.png Logo thumbnail from URL png ASCII dataset Resource Type 2021-03-30 revision 4.4 DataCite Metadata Working Group orginator resourceTypeGeneral LABORATORY > LABORATORY U.S. National Aeronautics and Space Administration Global Change Master Directory GCMD 2026-02-27 revision 23.4 NASA Global Change Master Directory orginator Valids List: Platforms ICARUS > Integrated Chamber Atmospheric data Repository for Unified Science U.S. National Aeronautics and Space Administration Global Change Master Directory GCMD 2026-02-27 revision 23.4 NASA Global Change Master Directory orginator Valids List: Projects EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES U.S. National Aeronautics and Space Administration Global Change Master Directory GCMD 2026-02-27 revision 23.4 NASA Global Change Master Directory orginator Valids List: Science and Services Keywords Creative Commons Attribution 4.0 International License None eng utf-8 environment 2014-01-21 2014-01-21 NSF NCAR Geoscience Data Exchange datahelp@ucar.edu https://gdex.ucar.edu distributor 2.351 https://gdex.ucar.edu/datasets/d789025/ https Dataset Description Related Link information https://gdex.ucar.edu/datasets/d789025/dataaccess/ https Data Access Related Link download none asNeeded