Identification

Title

Impact of Southern California anthropogenic emissions on ozone pollution in the mountain states: Model analysis and observational evidence from space

Abstract

The impact of Southern California (SoCal) anthropogenic emissions on ozone (O₃) in the mountain states in May 2010 is studied using the Sulfur Transport and Deposition Model. We identified two to six major transport events from SoCal to different subregions in the mountain states, with transport times of 0-2 days indicated by trajectories, time-lag correlations, and forward/adjoint sensitivities. Based on forward sensitivity analysis, the contributions from SoCal anthropogenic emissions to the monthly mean daily maximum 8 h average (MDA8) surface O₃ in the mountain states decrease with distance from SoCal, and they range from <1 ppbv (in Wyoming) to 15 ppbv (in western Arizona). These contributions show medium (>0.6) to strong (>0.8) positive correlations with the modeled total surface MDA8 O₃. For the most strongly affected states of Arizona and New Mexico, these contributions have median values of ∼3, ∼2, ∼5, and ∼15 ppbv when the total surface MDA8 O&#8323: exceeded thresholds of 60, 65, 70, and 75 ppbv, respectively. Surface MDA8 O&#832 ;values in SoCal show strong nonlinear responses to varied magnitudes of perturbation (e.g., ±50% and 100%) in SoCal anthropogenic emissions and weak nonlinear responses in the mountain states. Case studies show that different scales of transport (e.g., trans-Pacific, stratospheric intrusions, and interstate) can be dynamically and chemically coupled and simultaneously affect O₃ in the mountain states when the meteorological conditions are favorable. During some of these strong transport periods, the contributions of SoCal anthropogenic emissions to hourly O₃ in the mountain states can exceed 20 ppbv, close to the magnitude during a summer event reported by Langford et al. (2010). Satellite observations from the Tropospheric Emission Spectrometer and the Measurements of Pollution in the Troposphere multispectral retrievals qualitatively demonstrate large and interstate scales of transport, respectively. Suggestions are made for future satellite missions to measure O₃ with improved spatial coverage, temporal frequency, and near-surface sensitivity to provide better observational constraints on interstate pollution transport studies.

Resource type

document

Resource locator

Unique resource identifier

code

https://n2t.org/ark:/85065/d7rf5vxs

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

Keyword set

keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

End position

Dataset reference date

date type

publication

effective date

2013-11-27T00:00:00Z

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

version of format

Constraints related to access and use

Constraint set

Use constraints

Limitations on public access

None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact