Identification

Title

Impact of mixing and chemical change on ozone-tracer relations in the polar vortex

Abstract

Tracer-tracer relations have been used for a long time to separate physico-chemical change from change caused by transport processes. In particular, for more than a decade, ozone-tracer relations have been used to quantify chemical ozone loss in the polar vortex. The application of ozone-tracer relations for quantifying ozone loss relies on two hypotheses: that a compact ozone-tracer relation is established in the 'early' polar vortex and that any change of the ozone-tracer relation in the vortex over the course of winter is caused predominantly by chemical ozone loss. Here, we revisit this issue by analysing various sets of measurements and the results from several models. We find that mixing across the polar vortex edge impacts ozone-tracer relations in a way that may solely lead to an 'underestimation' of chemical ozone loss and not to an overestimation. Further, differential descent in the vortex and internal mixing has only a negligible impact on ozone loss estimates. Moreover, the representation of mixing in three-dimensional atmospheric models can have a substantial impact on the development of tracer relations in the model. Rather compact ozone-tracer relations develop – in agreement with observations – in the vortex of a Lagrangian model (CLaMS) where mixing is anisotropic and driven by the deformation of the flow. We conclude that, if a reliable 'early vortex' reference can be obtained and if vortex measurements are separated from mid-latitude measurements, ozone-tracer relations constitute a reliable tool for the quantitative determination of chemical ozone loss in the polar vortex.

Resource type

document

Resource locator

Unique resource identifier

code

https://n2t.org/ark:/85065/d7zs2x2k

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

Keyword set

keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

End position

Dataset reference date

date type

publication

effective date

2005-11-01T00:00:00Z

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

version of format

Constraints related to access and use

Constraint set

Use constraints

Copyright status for this publication is unknown. Please contact the author for further information.

Limitations on public access

None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata date

2025-07-17T17:06:49.483183

Metadata language

eng; USA