Identification

Title

An elevated reservoir of air pollutants over the Mid-Atlantic States during the 2011 DISCOVER-AQ campaign: Airborne measurements and numerical simulations

Abstract

During a classic heat wave with record high temperatures and poor air quality from July 18 to 23, 2011, an elevated reservoir of air pollutants was observed over and downwind of Baltimore, MD, with relatively clean conditions near the surface. Aircraft and ozonesonde measurements detected ∼120 ppbv ozone at 800 m altitude, but ∼80 ppbv ozone near the surface. High concentrations of other pollutants were also observed around the ozone peak: ∼300 ppbv CO at 1200 m, ∼2 ppbv NO₂ at 800 m, ∼5 ppbv SO₂ at 600 m, and strong aerosol optical scattering (2 × 10⁻⁴ m⁻¹) at 600 m. These results suggest that the elevated reservoir is a mixture of automobile exhaust (high concentrations of O₃, CO, and NO₂) and power plant emissions (high SO₂ and aerosols). Back trajectory calculations show a local stagnation event before the formation of this elevated reservoir. Forward trajectories suggest an influence on downwind air quality, supported by surface ozone observations on the next day over the downwind PA, NJ and NY area. Meteorological observations from aircraft and ozonesondes show a dramatic veering of wind direction from south to north within the lowest 5000 m, implying that the development of the elevated reservoir was caused in part by the Chesapeake Bay breeze. Based on in situ observations, CMAQ forecast simulations with 12 km resolution overestimated surface ozone concentrations and failed to predict this elevated reservoir; however, CMAQ research simulations with 4 km and 1.33 km resolution more successfully reproduced this event. These results show that high resolution is essential for resolving coastal effects and predicting air quality for cities near major bodies of water such as Baltimore on the Chesapeake Bay and downwind areas in the Northeast.

Resource type

document

Resource locator

Unique resource identifier

code

https://n2t.org/ark:/85065/d71j9ccv

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

Keyword set

keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

End position

Dataset reference date

date type

publication

effective date

2014-03-01T00:00:00Z

Frequency of update

Quality and validity

Lineage

Conformity

Data format

name of format

version of format

Constraints related to access and use

Constraint set

Use constraints

Limitations on public access

None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact