edu.ucar.opensky::articles:25946 UCAR/NCAR - Library OpenSky Support PO Box 3000 Boulder CO 80307-3000 opensky@ucar.edu http://opensky.ucar.edu/ homepage pointOfContact 2025-12-24T20:04:05.119041 ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data ISO 19115-2:2009(E) https://n2t.org/ark:/85065/d77w6h33 https://doi.org/10.5067/Suborbital/KORUSAQ/DATA01 https Related Dataset #1 Korea United States Air Quality Study https://doi.org/10.5281/zenodo.3701669 https Related Software #1 geoschem/geos-chem: GEOS-Chem 12.7.2 Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia 2022-09-08T00:00:00Z publication https://n2t.org/ark:/85065/d77w6h33 https://doi.org/10.1525/elementa.2022.00030 Kim, H. author Park, R. J. author Kim, S. author Brune, W. H. author Diskin, G. S. author Fried, A. author Hall, Samuel R. author Weinheimer, Andrew author Wennberg, P. author Wisthaler, A. author Blake, D. R. author Ullmann, Kirk author UCAR/NCAR - Library publisher We present a holistic examination of tropospheric OH reactivity (OHR) in South Korea using comprehensive NASA DC-8 airborne measurements collected during the Korea–United States Air Quality field study and chemical transport models. The observed total OHR (tOHR) averaged in the planetary boundary layer (PBL, <2.0 km) and free troposphere was 5.2 s1 and 2.0 s1 during the campaign, respectively.These values were higher than the calculated OHR (cOHR, 3.4 s1,1.0 s1) derived from trace-gas observations, indicating missing OHR fractions in the PBL and free troposphere of 35% and 50%, respectively. Incorporating nonobserved secondary species from the observationally constrained box model increased cOHR to 4.0 s1 in the PBL and 1.3 s1inthe freetroposphere. Simulated OHR (sOHR, 2.7 s1, 0.8 s1) was substantially lower than both tOHRandcOHRbyasmuchas60%.Thisunderestimate was substantialinthe free troposphere and marine boundary layer of the marginal sea (Yellow Sea).We then discuss the potential causes of unaccounted OHR. First, we suggest improving the accuracy of tropospheric reaction kinetics, which vary significantly in the available literature. Second, underestimated emissions of anthropogenic CO and oxygenated volatile organic compounds in East Asia contributed to the discrepancy between tOHR and sOHR. In addition, oxygenated and biogenic volatile organic compounds emitted from the marginal sea may contribute substantially to the regional OHR. Typical chemical transport models underestimate these sources, leading to a large missing OHR fraction. Despite this discrepancy, we found that simulated OH concentrations were comparable with those observed during the campaign because of slow OH recycling rates in the models; therefore, the models predicted less formation of photochemical oxidation products such as ozone. UCAR/NCAR - Library OpenSky Support PO Box 3000 Boulder CO 80307-3000 opensky@ucar.edu http://opensky.ucar.edu/ homepage pointOfContact PDF Text theme Resource Type 2016-01-01T00:00:00Z publication Copyright author(s). This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License. None eng geoscientificInformation