Identification

Title

Recent decreases in the growth rate of atmospheric HCFC‐22 column derived from the ground‐based FTIR harmonized retrievals at 16 NDACC sites

Abstract

HCFC‐22 is an ozone‐depleting substance with a greenhouse effect. The atmospheric mole fractions of HCFC‐22 have been increasing since the 1950s. Within the NDACC‐IRWG network, HCFC‐22 mol fractions can be retrieved from solar absorption spectra measured by ground‐based FTIR. However, only a few sites have provided HCFC‐22 data sets. Here, we demonstrate a harmonized FTIR HCFC‐22 retrieval strategy and generate a new global NDACC‐IRWG HCFC‐22 data set at 16 FTIR sites. The systematic and random uncertainties are 5.3%–8.7% and 3.2%–8.0%, respectively. A maximum HCFC‐22 column annual growth rate was observed in 2009 with a mean of 7.65 ± 1.39 ppt/year, and the HCFC‐22 annual growth rate decreased to 3.57 ± 1.39 ppt/year (2016–2020) and 2.15 ± 2.09 ppt/year (2021–2023). The annual growth rates derived from the FTIR measurements are compared to the ones derived from NOAA surface flask samplings and ACE‐FTS satellite measurements, and the three independent data sets show a good agreement.

Resource type

document

Resource locator

Unique resource identifier

code

https://n2t.net/ark:/85065/d74x5d2f

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

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keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

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Temporal extent

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date type

publication

effective date

2024-11-01T00:00:00Z

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<style type="text/css"></style><span style="font-family:Arial;font-size:10pt;font-style:normal;" data-sheets-root="1">Copyright author(s). This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.</span>

Limitations on public access

None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata date

2025-07-10T19:57:53.848575

Metadata language

eng; USA