Identification

Title

Development and evaluation of E3SM‐MOSAIC: Spatial distributions and radiative effects of nitrate aerosol

Abstract

Nitrate aerosol plays an important role in affecting regional air quality as well as Earth's climate. However, it is not well represented or even neglected in many global climate models. In this study, we couple the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) module with the four-mode version of the Modal Aerosol Module (MAM4) in DOE's Energy Exascale Earth System Model version 2 (E3SMv2) to simulate nitrate aerosol and its radiative effects. We find that nitrate aerosol simulated by E3SMv2-MAM4-MOSAIC is sensitive to the treatment of gaseous HNO3 transfer to/from interstitial particles related to accommodation coefficients of HNO3 (urn:x-wiley:19422466:media:jame21740:jame21740-math-0001) on dust and non-dust particles. We compare three different treatments of HNO3 transfer: (a) a treatment (MTC_SLOW) that uses a low urn:x-wiley:19422466:media:jame21740:jame21740-math-0002 in the mass transfer coefficient (MTC) calculation; (b) a dust-weighted MTC treatment (MTC_WGT) that uses a high urn:x-wiley:19422466:media:jame21740:jame21740-math-0003 on non-dust particles; and (c) a dust-weighted MTC treatment that also splits coarse mode aerosols into the coarse dust and sea salt sub-modes in MOSAIC (MTC_SPLC). MTC_WGT and MTC_SPLC increase the global annual mean (2005–2014) nitrate burden from 0.096 (MTC_SLOW) to 0.237 and 0.185 Tg N, respectively, mostly in the coarse mode. MTC_WGT and MTC_SPLC also produce stronger nitrate direct radiative forcing (−0.048 and −0.051 W m−2, respectively) and indirect forcing (−0.33 and −0.35 W m−2, respectively) than MTC_SLOW (−0.021 and −0.24 W m−2). MTC_WGT and MTC_SPLC improve nitrate surface concentrations over remote oceans based on limited observations and vertical profiles of nitrate concentrations against aircraft measurements below 400 hPa.

Resource type

document

Resource locator

Unique resource identifier

code

http://n2t.net/ark:/85065/d7z03d0x

codeSpace

Dataset language

eng

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

geoscientificInformation

Keywords

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keyword value

Text

originating controlled vocabulary

title

Resource Type

reference date

date type

publication

effective date

2016-01-01T00:00:00Z

Geographic location

West bounding longitude

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Temporal reference

Temporal extent

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End position

Dataset reference date

date type

publication

effective date

2022-11-01T00:00:00Z

Frequency of update

Quality and validity

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Conformity

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version of format

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Use constraints

Limitations on public access

None

Responsible organisations

Responsible party

contact position

OpenSky Support

organisation name

UCAR/NCAR - Library

full postal address

PO Box 3000

Boulder

80307-3000

email address

opensky@ucar.edu

web address

http://opensky.ucar.edu/

name: homepage

responsible party role

pointOfContact

Metadata on metadata

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