edu.ucar.opensky::articles:12415 UCAR/NCAR - Library OpenSky Support PO Box 3000 Boulder CO 80307-3000 opensky@ucar.edu http://opensky.ucar.edu/ homepage pointOfContact 2025-12-26T04:11:42.472351 ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data ISO 19115-2:2009(E) https://n2t.org/ark:/85065/d76d5ts8 Composition changes after the "Halloween" solar proton event: The High Energy Particle Precipitation in the Atmosphere (HEPPA) model versus MIPAS data intercomparison study 2011-09-05T00:00:00Z publication https://n2t.org/ark:/85065/d76d5ts8 https://doi.org/10.5194/acp-11-9089-2011 Funke, B. author Baumgaertner, A. author Calisto, M. author Egorova, T. author Jackman, C. author Kieser, J. author Krivolutsky, A. author López-Puertas, M. author Marsh, Daniel author Reddmann, T. author Rozanov, E. author Salmi, S. author Sinnhuber, M. author Stiller, G. author Verronen, P. author Versick, S. author von Clarmann, T. author Vyushkova, T. author Wieters, N. author Wissing, J. author UCAR/NCAR - Library publisher We have compared composition changes of NO, NO₂, H₂O₂, O₃, N₂O, HNO₃, N₂O₅, HNO₄, ClO, HOCl, and ClONO₂ as observed by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat in the aftermath of the "Halloween" solar proton event (SPE) in late October 2003 at 25–0.01 hPa in the Northern Hemisphere (40–90° N) and simulations performed by the following atmospheric models: the Bremen 2-D model (B2dM) and Bremen 3-D Chemical Transport Model (B3dCTM), the Central Aerological Observatory (CAO) model, FinROSE, the Hamburg Model of the Neutral and Ionized Atmosphere (HAMMONIA), the Karlsruhe Simulation Model of the Middle Atmosphere (KASIMA), the ECHAM5/MESSy Atmospheric Chemistry (EMAC) model, the modeling tool for SOlar Climate Ozone Links studies (SOCOL and SOCOLi), and the Whole Atmosphere Community Climate Model (WACCM4). The large number of participating models allowed for an evaluation of the overall ability of atmospheric models to reproduce observed atmospheric perturbations generated by SPEs, particularly with respect to NOy and ozone changes. We have further assessed the meteorological conditions and their implications for the chemical response to the SPE in both the models and observations by comparing temperature and tracer (CH₄ and CO) fields. Simulated SPE-induced ozone losses agree on average within 5 % with the observations. Simulated NOy enhancements around 1 hPa, however, are typically 30 % higher than indicated by the observations which are likely to be related to deficiencies in the used ionization rates, though other error sources related to the models' atmospheric background state and/or transport schemes cannot be excluded. The analysis of the observed and modeled NOy partitioning in the aftermath of the SPE has demonstrated the need to implement additional ion chemistry (HNO₃ formation via ion-ion recombination and water cluster ions) into the chemical schemes. An overestimation of observed H₂O₂ enhancements by all models hints at an underestimation of the OH/HO₂ ratio in the upper polar stratosphere during the SPE. The analysis of chlorine species perturbations has shown that the encountered differences between models and observations, particularly the underestimation of observed ClONO₂ enhancements, are related to a smaller availability of ClO in the polar night region already before the SPE. In general, the intercomparison has demonstrated that differences in the meteorology and/or initial state of the atmosphere in the simulations cause a relevant variability of the model results, even on a short timescale of only a few days. UCAR/NCAR - Library OpenSky Support PO Box 3000 Boulder CO 80307-3000 opensky@ucar.edu http://opensky.ucar.edu/ homepage pointOfContact PDF Text theme Resource Type 2016-01-01T00:00:00Z publication Copyright Author(s) 2011. This work is distributed under the Creative Commons Attribution 3.0 License. None eng geoscientificInformation