ICARUS Chamber Experiment: Caltech Atmospheric Chamber_20140724_Methacrylolyl peroxynitrate (MPAN)/ALPHA-PINENE/hydrogen peroxide/Methacrylic acid epoxide (MAE)_Hydroxyl radical_No Seed_Dry
d789086
Goals:; This experiment was done to photooxidize MPAN and capture NO3 with a-pinene, while observing secondary organic aerosol (SOA) formation through dry nucleation. MAE was added toward the end of the experiment to see if it enhanced SOA formation. Summary:; Addition of MAE didn't change the particle mass. Similar to 7/22 - we observed m/z 316, the pinene nitroxyhydroperoxide on CIMS, which showed that NO3 radical was liberated from the MPAN + OH reaction. This reaction produced a lot of SOA. Organization: Caltech Atmospheric Chamber; Lab Affiliation: California Institute of Technology, Pasadena, CA; Chamber: Near/Far Bag 2012-2015 (Tran) Experiment Category: Gas phase chemical reaction, Aerosol formation; Oxidant: Hydroxyl radical; Reactants: Methacrylolyl peroxynitrate (MPAN), ALPHA-PINENE, hydrogen peroxide, Methacrylic acid epoxide (MAE); Reaction Type: Photooxidation; Relative Humidity: 4; Temperature: 15; Pressure: 750 Torr
dataset
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dataset
revision
2014-10-16
LABORATORY > LABORATORY
revision
2025-06-17
ICARUS > Integrated Chamber Atmospheric data Repository for Unified Science
revision
2025-06-18
EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES
revision
2025-06-09
2014-07-24
2014-07-24
publication
2023-08-23
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Creative Commons Attribution 4.0 International License
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UCAR/NCAR - Research Data Archive
National Center for Atmospheric Research
CISL/DECS
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Boulder
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U.S.A.
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303-497-1291
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NCAR Research Data Archive
National Center for Atmospheric Research
CISL/DECS
P.O. Box 3000
Boulder
80307
U.S.A.
303-497-1291
name: NCAR Research Data Archive
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2025-06-24T21:05:02Z