Identification

Title

ICARUS Chamber Experiment: Nguyen Group_20220727_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/2-(3-Acetyl-2,2-dimethylcyclobutyl)acetaldehyde_Nitrate radical_Ammonium sulfate

Alternative title(s)

d789204

Abstract

<p>Goals:<br/> To quantify SOA yield and gas-phase product yields (particularly of organonitrates) from humid nighttime RO2+HO2-dominated NO3-initiated chemistry of pinonaldehyde.</p> <p>Summary:<br/> The chamber was humidified, after which H2O2, NO2, and O3 were injected in the chamber and allowed to equilibrate, forming NO3 and HO2. Ammonium sulfate seed particles were injected. Then pinonaldehyde was injected and decayed by reaction with NO3. Gas phase organics were monitored by CF3O- CIMS (units: normalized counts), particle formation was monitored by SMPS, and RH / T / O3 / NOx were monitored throughout.</p> <p>O3/NOx data sometimes require post-correction not applied here, including subtraction of an ozone interference from H2O2 (1 ppm H2O2 is detected as about 12 ppb ozone) and correction for an in-line HEPA filter (see timeline for applicable timing) that scrubs about 10% of NO2 and 45% of ozone.</p> <p>Organization: Nguyen Group<br/> Lab Affiliation: UC Davis<br/> Chamber: Tran's big bag of air</p> <p>Experiment Category: Gas phase chemical reaction, Aerosol formation<br/> Oxidant: Nitrate radical<br/> Reactants: Nitrogen Dioxide, Ammonium Sulfate, Ozone, Hydrogen Peroxide, 2-(3-Acetyl-2,2-dimethylcyclobutyl)acetaldehyde<br/> Reaction Type: Dark oxidation<br/> Relative Humidity: 66<br/> Temperature: 22<br/> Seed Name: Ammonium sulfate<br/> Pressure: approximate 1 atm</p>

Resource type

dataset

Resource locator

https://gdex.ucar.edu/datasets/d789204/

protocol: https

name: Dataset Description

description: Related Link

function: information

https://gdex.ucar.edu/datasets/d789204/dataaccess/

protocol: https

name: Data Access

description: Related Link

function: download

Unique resource identifier

code

codeSpace

Dataset language

Spatial reference system

code identifying the spatial reference system

Classification of spatial data and services

Topic category

environment

Keywords

Keyword set

keyword value

dataset

originating controlled vocabulary

title

reference date

date type

revision

effective date

2021-03-30

Keyword set

keyword value

LABORATORY > LABORATORY

originating controlled vocabulary

title

reference date

date type

revision

effective date

2025-10-03

Keyword set

keyword value

ICARUS > Integrated Chamber Atmospheric data Repository for Unified Science

originating controlled vocabulary

title

reference date

date type

revision

effective date

2025-10-03

Keyword set

keyword value

EARTH SCIENCE > ATMOSPHERE > ATMOSPHERIC CHEMISTRY > TRACE GASES/TRACE SPECIES

originating controlled vocabulary

title

reference date

date type

revision

effective date

2025-10-03

Geographic location

West bounding longitude

East bounding longitude

North bounding latitude

South bounding latitude

Temporal reference

Temporal extent

Begin position

2022-07-27

End position

2022-07-27

Dataset reference date

date type

publication

effective date

2023-03-07

Frequency of update

notPlanned

Quality and validity

Lineage

Conformity

Data format

name of format

version of format

Constraints related to access and use

Constraint set

Use constraints

Creative Commons Attribution 4.0 International License

Limitations on public access

None

Responsible organisations

Responsible party

organisation name

email address

datahelp@ucar.edu

responsible party role

pointOfContact

Metadata on metadata

Metadata point of contact

organisation name

NSF NCAR Geoscience Data Exchange

email address

datahelp@ucar.edu

web address

https://gdex.ucar.edu

name: NSF NCAR Geoscience Data Exchange

description: The Geoscience Data Exchange (GDEX), managed by the Computational and Information Systems Laboratory (CISL) at NSF NCAR, contains a large collection of meteorological, atmospheric composition, and oceanographic observations, and operational and reanalysis model outputs, integrated with NSF NCAR High Performance Compute services to support atmospheric and geosciences research.

function: download

responsible party role

pointOfContact

Metadata date

2025-10-09T01:38:40Z

Metadata language