edu.ucar.opensky::articles:22434 UCAR/NCAR - Library OpenSky Support PO Box 3000 Boulder CO 80307-3000 opensky@ucar.edu http://opensky.ucar.edu/ homepage pointOfContact 2025-12-25T15:37:12.934201 ISO 19115-2 Geographic Information - Metadata - Part 2: Extensions for Imagery and Gridded Data ISO 19115-2:2009(E) https://n2t.org/ark:/85065/d79w0jh7 https://doi.org/10.15142/T33H26 https Related Dataset #1 USU Na Lidar Data Photochemistry on the bottom side of the mesospheric Na layer 2019-03-25T00:00:00Z publication https://n2t.org/ark:/85065/d79w0jh7 https://doi.org/10.5194/acp-19-3769-2019 Yuan, T. author Feng, Wuhu author Plane, J. M. C. author Marsh, Daniel author UCAR/NCAR - Library publisher Lidar observations of the mesospheric Na layer have revealed considerable diurnal variations, particularly on the bottom side of the layer, where more than an order-of-magnitude increase in Na density has been observed below 80 km after sunrise. In this paper, multi-year Na lidar observations are utilized over a full diurnal cycle at Utah State University (USU) (41.8 degrees N, 111.8 degrees W) and a global atmospheric model of Na with 0.5 km vertical resolution in the mesosphere and lower thermosphere (WACCM-Na) to explore the dramatic changes of Na density on the bottom side of the layer. Photolysis of the principal reservoir NaHCO3 is shown to be primarily responsible for the increase in Na after sunrise, amplified by the increased rate of reaction of NaHCO3 with atomic H, which is mainly produced from the photolysis of H2O and the reaction of OH with O-3. This finding is further supported by Na lidar observation at USU during the solar eclipse (> 96% totality) event on 21 August 2017, when a decrease and recovery of the Na density on the bottom side of the layer were observed. Lastly, the model simulation shows that the Fe density below around 80 km increases more strongly and earlier than observed Na changes during sunrise because of the considerably faster photolysis rate of its major reservoir of FeOH. UCAR/NCAR - Library OpenSky Support PO Box 3000 Boulder CO 80307-3000 opensky@ucar.edu http://opensky.ucar.edu/ homepage pointOfContact PDF Text theme Resource Type 2016-01-01T00:00:00Z publication Copyright 2019 Author(s). This work is licensed under a Creative Commons Attribution 4.0 International license. None eng geoscientificInformation