Emission estimates of HCFCs and HFCs in California from the 2010 CalNex study

The CalNex 2010 (California Research at the Nexus of Air Quality and Climate Change) study was designed to evaluate the chemical composition of air masses over key source regions in California. During May to June 2010, air samples were collected on board a National Oceanic and Atmospheric Administration (NOAA) WP-3D aircraft over the South Coast Air Basin of California (SoCAB) and the Central Valley (CV). This paper analyzes six effective greenhouse gases—chlorodifluoromethane (HCFC-22), 1,1-dichloro-1-fluoroethane (HCFC-141b), 1-chloro-1,1-difluoroethane (HCFC-142b), 2-chloro-1,1,1,2-tetrafluoroethane (HCFC-124), 1,1,1,2-tetrafluoroethane (HFC-134a), and 1,1-difluoroethane (HFC-152a)—providing the most comprehensive characterization of chlorofluorocarbon (CFC) replacement compound emissions in California. Concentrations of measured HCFCs and HFCs are enhanced greatly throughout the SoCAB and CV, with highest levels observed in the SoCAB: 310 ± 92 pptv for HCFC-22, 30.7 ± 18.6 pptv for HCFC-141b, 22.9 ± 2.0 pptv for HCFC-142b, 4.86 ± 2.56 pptv for HCFC-124, 109 ± 46.4 pptv for HFC-134a, and 91.2 ± 63.9 pptv for HFC-152a. Annual emission rates are estimated for all six compounds in the SoCAB using the measured halocarbon to carbon monoxide (CO) mixing ratios and CO emissions inventories. Emission rates of 3.05 ± 0.70 Gg for HCFC-22, 0.27 ± 0.07 Gg for HCFC-141b, 0.06 ± 0.01 Gg for HCFC-142b, 0.11 ± 0.03 Gg for HCFC-124, 1.89 ± 0.43 Gg for HFC-134a, and 1.94 ± 0.45 Gg for HFC-152b for the year 2010 are calculated for the SoCAB. These emissions are extrapolated from the SoCAB region to the state of California using population data. Results from this study provide a baseline emission rate that will help future studies determine if HCFC and HFC mitigation strategies are successful.

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Author Barletta, Barbara
Carreras-Sospedra, Marc
Cohan, Alex
Nissenson, Paul
Dabdub, Donald
Meinardi, Simone
Atlas, Elliot
Lueb, Richard
Holloway, John
Ryerson, Thomas
Pederson, James
VanCuren, Richard
Blake, Donald
Publisher UCAR/NCAR - Library
Publication Date 2013-02-27T00:00:00
Digital Object Identifier (DOI) Not Assigned
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Topic Category geoscientificInformation
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Metadata Date 2023-08-18T18:07:22.250540
Metadata Record Identifier edu.ucar.opensky::articles:12667
Metadata Language eng; USA
Suggested Citation Barletta, Barbara, Carreras-Sospedra, Marc, Cohan, Alex, Nissenson, Paul, Dabdub, Donald, Meinardi, Simone, Atlas, Elliot, Lueb, Richard, Holloway, John, Ryerson, Thomas, Pederson, James, VanCuren, Richard, Blake, Donald. (2013). Emission estimates of HCFCs and HFCs in California from the 2010 CalNex study. UCAR/NCAR - Library. http://n2t.net/ark:/85065/d7zc83q9. Accessed 11 February 2025.

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