ICARUS Chamber Experiment: 2014 FIXCIT Study_20140111_nitric oxide/ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Alpha-pinene + OH, high NO, dry, (NH4)2SO4 seed at end

Goals: High NO oxidation of alpha-pinene to test products. Interested mainly in: organic nitrate yield from alpha-pinene at the high NO limit -products formed in high NO oxidation of alpha-pinene to confirm for CIMS instruments what potential products formed in SOAS -potential contribution of alpha-pinene derived nitrates to particle phase nitrates seen at SOAS. Secondary goals: potential effect of addition of seed aerosol on apparent loss rate of gas-phase compounds

Summary: The initial measurements of alpha -pinene and alkyl nitrates appeared to go well for PTR-MS and TD-LIF. Ozone began creeping up about ~30min into the experiment, reaching a maximum <90ppbv O3. NO was injected in after about an hour and 15 minutes after lights on to titrate out the ozone. Particle nucleation was observed roughly ~1hr 15min into the oxidation, potentially from an OH spike from the NO injection due to PNA buildup. After 08 ~5hrs of oxidation, the lights were turned off. Thirty minutes of dark sampling followed, at which point ammonium sulfate seed was injected into the chamber to determine what effect, if any, this will have on wall-loss of various species.

Organization: 2014 FIXCIT Study Lab Affiliation: California Institute of Technology Chamber: Seinfeld chambers

Experiment Category: Gas phase chemical reaction Oxidant: Hydroxyl radical Reactants: nitric oxide, ALPHA-PINENE, hydrogen peroxide Reaction Type: Photooxidation Relative Humidity: 5 Temperature: 26 Pressure: 755

To Access Resource:

Questions? Email Resource Support Contact:

  • Nguyen, Tran
    tbn@ucdavis.edu
    2014 FIXCIT Study

Temporal Range

  • Begin:  2014-01-11
    End:  2014-01-11

Keywords

Resource Type dataset
Temporal Range Begin 2014-01-11
Temporal Range End 2014-01-11
Temporal Resolution N/A
Bounding Box North Lat N/A
Bounding Box South Lat N/A
Bounding Box West Long N/A
Bounding Box East Long N/A
Spatial Representation N/A
Spatial Resolution N/A
Related Links

Publication : Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds

Publication : Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere

Publication : Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests?
Additional Information N/A
Resource Format Compressed Archive File (application/zip)
Standardized Resource Format Archive
Asset Size N/A
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Creative Commons Attribution 4.0 International License.
Access Constraints These data are openly accessible by all registered users. Accounts are available free of charge following the registration of user information with a valid email address.
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Resource Support Name Nguyen, Tran
Resource Support Email tbn@ucdavis.edu
Resource Support Organization 2014 FIXCIT Study
Distributor N/A
Metadata Contact Name GDEX Curator
Metadata Contact Email datahelp@ucar.edu
Metadata Contact Organization UCAR/NCAR - GDEX

Author Wennberg, Paul
Seinfeld, John
Crounse, John
Nguyen, Tran
Publisher ICARUS Community
Publication Date 2021-10-12
Digital Object Identifier (DOI) https://doi.org/10.5065/30ky-9h23
Alternate Identifier N/A
Resource Version N/A
Topic Category N/A
Progress N/A
Metadata Date 2022-01-27T09:12:22-07:00
Metadata Record Identifier edu.ucar.gdex::b64589c0-e610-44db-b6b8-0d80a4df2ccb
Metadata Language eng; USA
Suggested Citation Wennberg, Paul, Seinfeld, John, Crounse, John, Nguyen, Tran. (2021). ICARUS Chamber Experiment: 2014 FIXCIT Study_20140111_nitric oxide/ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Alpha-pinene + OH, high NO, dry, (NH4)2SO4 seed at end. ICARUS Community. https://doi.org/10.5065/30ky-9h23. Accessed 20 April 2024.

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