ICARUS Chamber Experiment: 2014 FIXCIT Study_20140111_nitric oxide/ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Alpha-pinene + OH, high NO, dry, (NH4)2SO4 seed at end

Goals:; High NO oxidation of alpha-pinene to test products. Interested mainly in: organic nitrate yield from alpha-pinene at the high NO limit; -products formed in high NO oxidation of alpha-pinene to confirm for CIMS instruments what potential products formed in SOAS; -potential contribution of alpha-pinene derived nitrates to particle phase nitrates seen at SOAS. Secondary goals: potential effect of addition of seed aerosol on apparent loss rate of gas-phase compounds

Summary:; The initial measurements of alpha -pinene and alkyl nitrates appeared to go well for PTR-MS and TD-LIF. ; Ozone began creeping up about ~30min into the experiment, reaching a maximum < 90 ppbv O3. NO was injected in after about an hour and 15 minutes after lights on to titrate out the ozone. Particle nucleation was observed roughly ; ~1hr 15min into the oxidation, potentially from an OH spike from the NO injection due to PNA buildup. ; After 08 ~5hrs of oxidation, the lights were turned off. Thirty minutes of dark sampling followed, at which ; point ammonium sulfate seed was injected into the chamber to determine ; what effect, if any, this will have on wall-loss of various species.

Organization: 2014 FIXCIT Study; Lab Affiliation: California Institute of Technology; Chamber: Seinfeld chambers

Experiment Category: Gas phase chemical reaction; Oxidant: Hydroxyl radical; Reactants: nitric oxide, ALPHA-PINENE, hydrogen peroxide; Reaction Type: Photooxidation; Relative Humidity: 5; Temperature: 26; Seed Name: No Seed; Pressure: 755

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Questions? Email Resource Support Contact:

  • Bob Dattore
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    UCAR/NCAR - Research Data Archive

Temporal Range

  • Begin:  2014-01-11
    End:  2014-01-11

Keywords

Resource Type dataset
Temporal Range Begin 2014-01-11
Temporal Range End 2014-01-11
Temporal Resolution N/A
Bounding Box North Lat N/A
Bounding Box South Lat N/A
Bounding Box West Long N/A
Bounding Box East Long N/A
Spatial Representation N/A
Spatial Resolution N/A
Related Links

Related Resource #1 : ICARUS Dataset at UC-Davis
Additional Information N/A
Resource Format ASCII
Standardized Resource Format ASCII
Asset Size 0.00 MB
Legal Constraints

Creative Commons Attribution 4.0 International License
Access Constraints None
Software Implementation Language N/A

Resource Support Name Bob Dattore
Resource Support Email dattore@ucar.edu
Resource Support Organization UCAR/NCAR - Research Data Archive
Distributor NCAR Research Data Archive
Metadata Contact Name N/A
Metadata Contact Email rdahelp@ucar.edu
Metadata Contact Organization NCAR Research Data Archive

Author Wennberg, Paul O.
Seinfeld, John H.
Crounse, John D.
Nguyen, Tran B.
Publisher Research Data Archive at the National Center for Atmospheric Research, Computational and Information Systems Laboratory
Publication Date 2024-04-30
Digital Object Identifier (DOI) https://doi.org/10.5065/30ky-9h23
Alternate Identifier d789022
Resource Version N/A
Topic Category environment
Progress completed
Metadata Date 2025-06-19T02:05:02Z
Metadata Record Identifier edu.ucar.rda::d789022
Metadata Language eng; USA
Suggested Citation Wennberg, Paul O., Seinfeld, John H., Crounse, John D., Nguyen, Tran B.. (2024). ICARUS Chamber Experiment: 2014 FIXCIT Study_20140111_nitric oxide/ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Alpha-pinene + OH, high NO, dry, (NH4)2SO4 seed at end. Research Data Archive at the National Center for Atmospheric Research, Computational and Information Systems Laboratory. https://doi.org/10.5065/30ky-9h23. Accessed 22 June 2025.

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