Horizontal dispersion of buoyant materials in the ocean surface boundary layer

The horizontal dispersion of materials with a constant rising speed under the exclusive influence of ocean surface boundary layer (OSBL) flows is investigated using both three-dimensional turbulence-resolving Lagrangian particle trajectories and the classical theory of dispersion in bounded shear currents generalized for buoyant materials. Dispersion in the OSBL is caused by the vertical shear of mean horizontal currents and by the turbulent velocity fluctuations. It reaches a diffusive regime when the equilibrium vertical material distribution is established. Diffusivity from the classical shear dispersion theory agrees reasonably well with that diagnosed using three-dimensional particle trajectories. For weakly buoyant materials that can be mixed into the boundary layer, shear dispersion dominates turbulent dispersion. For strongly buoyant materials that stay at the ocean surface, shear dispersion is negligible compared to turbulent dispersion. The effective horizontal diffusivity due to shear dispersion is controlled by multiple factors, including wind speed, wave conditions, vertical diffusivity, mixed layer depth, latitude, and buoyant rising speed. With all other meteorological and hydrographic conditions being equal, the effective horizontal diffusivity is larger in wind-driven Ekman flows than in wave-driven Ekman-Stokes flows for weakly buoyant materials and is smaller in Ekman flows than in Ekman-Stokes flows for strongly buoyant materials. The effective horizontal diffusivity is further reduced when enhanced mixing by breaking waves is included. Dispersion by OSBL flows is weaker than that by submesoscale currents at a scale larger than 100 m. The analytic framework will improve subgrid-scale modeling in realistic particle trajectory models using currents from operational ocean models.